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This document discusses methods for separating lanthanide ions using ion exchange and solvent extraction A process known as ion exchange is then used to separate the lanthanides from each other. In ion exchange, lanthanide ions in solution are passed through a resin column and interact differently with the resin based on their size, allowing for separation.
In this technical note, methods are presented for the separation of lanthanides by both anion and anion exchange To separate the lanthanides from other elements occurring with them, they are chemically combined with specific substances to form lanthanide compounds with low solubility (oxalates and fluorides, for example) Depending on the ratios of the lanthanide elements in a particular sample, either method may be preferred.
In this study, an electromagnetic isotope separation technique was applied after neutron irradiation to boost the specific activity by separating 169er from 168er targets.
Key separation methods described include precipitation, thermal reactions, complex formation, solvent extraction, valency change, and ion exchange Ion exchange is highlighted as the most important, rapid, and effective general method for separating and purifying lanthanide elements. The hydrated lanthanum ion, being smallest, binds most tightly to the resin, whereas the largest hydrated ion, lutetium, binds the weakest The lanthanides are then washed out of the ion exchange column with various solutions, emerging one at a time, and so are separated.
In this method, synthetic cation resins are used These resins contain s o 3 h / c o o h groups The hydrogen in these resins is replaced with lanthanide ions.
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